Abstract

Title Chemical Reaction between Potassium Aluminosilicates and Aggregates at Different Temperatures
Thematic area Basic Science
Presenter Mr. Yiming Yin
Authors Mr. Yiming Yin, Zhengzhou University, Zhengzhou - China
Mr. Ye Li, Zhengzhou University, Zhengzhou - China
Prof. Suping Li, Zhengzhou University, Zhengzhou - China
Mr. Pengtao Zhai, Zhengzhou University, Zhengzhou - China
Mr. Liugang Chen, Zhengzhou University, Zhengzhou - China
Mr. Guotian Ye, Zhengzhou University, Zhengzhou - China
Abstract

Kalsilite/kaliophilite (KAlSiO4, KAS) could be used in saggars for the calcination of Li(NixCoyMnz)O2 ternary battery materials because kalsilite has high melting point (1750°C) and could be chemically resistant to such ternary battery materials. However, the compatibility of KAS with the commonly used aggregates in the saggars is not clear. In this work, KAS was synthesized using potassium carbonate (K2CO3), silica and alumina. Then the as-synthesized KAS fine powder was mixed with four kinds of aggregates (alumina, mullite, cordierite and magnesia-alumina spinel) respectively. The mixtures were fired at temperatures between 700°C and 1200°C and subsequently examined by means of XRD and SEM to investigate the reaction between the KAS fine powder and various aggregates.